Viologen photooxidation of thiacarbocyanine dyes and their supramolecular complexes with cucurbit[8]uril

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Resumo

The photooxidation reaction of 3,3'-diethyl-9–methylthiacarbocyanine and 3,3'-diethylthiacarbocyanine by viologenes (methyl viologenes, p-chlorophenyl viologenes, p-cyanophenyl viologenes) in acetonitrile and their dimeric complexes with cucurbit[8]uril by monomeric complexes of viologenes in presence of cucurbit[8]uril in water has been studied. The products of photooxidation of dye monomers in acetonitrile are dye dication-radicals and cation-radicals of viologens. The photooxidation of dimeric complexes produces trication radicals of dimeric complexes and cation radicals of monomeric complexes of viologens. The most efficient reaction is the photooxidation of dyes in acetonitrile.

Sobre autores

G. Zakharova

“Kurchatov Institute” National Research Center

Autor responsável pela correspondência
Email: gvzakharova@gmail.com

Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department

Rússia, Moscow, 119421

T. Fedotova

“Kurchatov Institute” National Research Center

Email: tatyana.fedotova@phystech.edu

Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department

Rússia, Moscow, 119421

A. Chibisov

“Kurchatov Institute” National Research Center

Email: alexander.chibisov@gmail.com

Kurchatov Complex “Crystallography and Photonics”, Photochemistry Center Department

Rússia, Moscow, 119421

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