Alumina in Active Center Formation of Cobalt Catalysts for Fischer–Tropsch Synthesis

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

A mini-review is devoted to the role of alumina as a support or a binder in cobalt catalysts for Fischer–Tropsch synthesis, in particular the role in the formation of active centers. Some peculiarities of the physico-chemical properties of alumina have been identified, which may be useful in the development of new catalysts. The possibilities for improving catalytic properties by optimizing the shape and size of particles, as well as the degree of reduction of Co when using alumina as a support or a support component are demonstrated. Bibliography: 75 references

Full Text

Restricted Access

About the authors

L. V. Sineva

NRC “KURCHATOV INSTITUTE” — TISNCM

Author for correspondence.
Email: sinevalv@tisnum.ru
Russian Federation, Tsentralnaya st., 7a, Moscow, Troistk, 108840

E. Y. Asalieva

NRC “KURCHATOV INSTITUTE” — TISNCM

Email: sinevalv@tisnum.ru
Russian Federation, Tsentralnaya st., 7a, Moscow, Troistk, 108840

V. Z. Mordkovich

NRC “KURCHATOV INSTITUTE” — TISNCM

Email: sinevalv@tisnum.ru
Russian Federation, Tsentralnaya st., 7a, Moscow, Troistk, 108840

References

  1. Cheng K., Kang J., King D.L., Subramanian V., Zhou C., Zhang Q., Wang Y. // Adv. Catal. 2017. V. 60. P. 125. doi: 10.1016/bs.acat.2017.09.003
  2. Senecal P., Jacques S.D.M., Michiell M.D., Kimber S.A.J., Vamvakeros A., Odarchenko Y., Lezcano-Gonzalez I., Paterson J., Ferguson E., Beale A.M. // ACS Catal. 2017. V. 7. № 4. P. 2284.
  3. Tsakoumis N.E., Voronov A., Ronning M., van Beek W., Borg O., Rytter E., Holmen A. // J. Catal. 2012. V. 291. P. 138.
  4. Fischer N., Clapham B., Feltes T., Claeys M. // ACS Catal. 2015. V. 5. № 1. P. 113.
  5. Sadeqzadeh M., Karaca H., Safonova O.V., Fongarland P., Chambrey S., Roussel P., Griboval-Constant A., Lacroix M., Curulla-Ferré D., Luck F., Khodakov A.Y. // Catal. Today. 2011. V. 164. P. 62.
  6. Cats K.H., Gonzalez-Jimenez I. D., Liu Y., Nelson J., van Campen D., Meirer F., van der Eerden A.M.J., de Groot F.M.F., Andrews J.C., Weckhuysen B.M. // Chem. Commun. 2013. V. 49. № 41. P. 4622.
  7. Shiba N.C., Liu X., Mao H., Qian X., Hildebrandt D., Yao Y. // Fuel. 2022 V. 320. Art. 123939.
  8. Jacobs G., Das T.K., Zhang Y., Li J., Racoillet G., Davis B.H. // Appl. Catal. A: Gen. 2002. V. 233. P. 263.
  9. Chen W., Lin T., Dai Y., An Y., Yu F., Zhong L., Li S., Sun Y. // Catal. Today. 2018. V. 311. P. 8.
  10. Yang N., Bent S. F. // J. Catal. 2017. V. 351. P. 49.
  11. Cheng Q., Liu Y., Lyu S., Tian Y., Ma Q., Li X. // Chin. J. Chem. Eng. 2021. V. 35. P. 220.
  12. Munirathinam R., Minh D.P., Nzihou A. // Ind. Eng. Chem. Res. 2018. V. 57. № 48 P. 16137.
  13. Nikolopoulos N., Wickramasinghe A., Whiting G.T., Weckhuysen B.M. // Catal. Sci. Technol. 2023. V. 13. № 3. P. 862.
  14. Lakiss L., Gilson J.-P., Valtchev V., Mintova S., Vicente A., Vimont A., Bedard R., Abdo S., Bricker J. // Micropor. Mesopor. Mater. 2020. V. 299. Art. 110114.
  15. Hargreaves J.S.J., Munnoch A.L. // Catal. Sci. Technol. 2013. V. 3. P. 1165.
  16. Shihabi D.S., Garwood W.E., Chu P., Miale J. N., Lago R.M., Chu C.T.-W., Chang C. D. // J. Catal. 1985. V. 93. P. 471.
  17. Jacobs G., Ji Y., Davis B.H., Cronauer D., Kropf A.J., Marshall C.L. // Appl. Catal. A: Gen. 2007. V. 333. P. 177.
  18. Shiba N.C., Liu X., Yao Y. // Reactions. 2023. V. 4. P. 420.
  19. Lögdberg S., Yang J., Lualdi M., Walmsley J.C., Järås S., Boutonnet M., Blekkan E.A., Rytter E., Holmen A. // J. Catal. A: Gen. 2017. V. 352. P. 515.
  20. Shiba N.C., Liu X., Hildebrandt D., Yao Y. // Reactions. 2021. V. 2. P. 258.
  21. Braconnier L., Landrivon E., Clémençon I., Legens C., Diehl F., Schuurman Y. // Catal. Today. 2013. V. 215. P. 18.
  22. Storsæter S., Tøtdal B., Walmsley J.C., Tanem B.S., Holmen A. // J. Catal. 2005. V. 236. № 1. P. 139.
  23. ten Have I.C., Weckhuysen B.M. // Chem. Catal. 2021. V. 1. № 2. P. 339.
  24. Liu J.-X., Wang P., Xu W., Hensen E.J.M. // Engineering. 2017. V. 3. № 4. P. 467.
  25. Kitakami O., Sato H., Shimada Y., Sato F., Tanaka M. // Phys. Rev. B. 1997. V. 56. № 21. P. 13849.
  26. Fischer N., van Steen E., Claeys M. // Catal. Today. 2011. V. 171. № 1. P. 174.
  27. Lyu S., Wang L., Zhang J., Liu C., Sun J., Peng B., Wang Y., Rappé K.G., Zhang Y., Li J., Nie L. // ACS Catal. 2018. V. 8. P. 7787.
  28. Liu Y., Chen C., Hou B., Jia L., Wang J., Ma Z., Wang Q., Li D. // Mol. Catal. 2023. V. 544. Art. 113184.
  29. Gnanamani M.K., Jacobs G., Shafer W.D., Davis B.H. // Catal. Today. 2013. V. 215. P. 13.
  30. Du H., Jiang M., Zhu H., Huang C., Zhao Z., Dong W., Lu W., Liu T., Zhang Z.C., Ding Y. // Fuel. 2021. V. 292. Art. 1202443.
  31. Liu J., Su H., Sun D., Zhang B., Li W. // J. Am. Chem. Soc. 2013. V. 135. № 44. P. 16284.
  32. Patanou E., Tsakoumis N.E., Myrstad R., Blekkan E.A. // Appl. Catal. A: Gen. 2018. V. 549. P. 280.
  33. van Helden P., Ciobîcă I.M., Coetzer R.L.J. // Catal. Today. 2016. V. 261. P. 48.
  34. Ma C., Yun Y., Zhang T., Suo H., Yan L., Shen X., Li Y., Yang Y. // ChemCatChem. 2021. V. 13. P. 4350.
  35. Karaca H., Safonova O.V., Chambrey S., Fongarland P., Roussel P., Griboval-Constant A., Lacroix M., Khodakov A.Y. // J. Catal. 2011. V. 277. № 1. P. 14.
  36. Булавченко О.А., Черепанова С.В. Малахов В.В., Довлитова Л.С. Ищенко А.В., Цыбуля С.В. // Кинетика и катализ. 2009. Т. 50. № 2. C. 205.
  37. Кобозев Н. И. // Ж. физ. химии. 1939. Т. 13. С. 1.
  38. Weststrate C.J., Mahmoodinia M., Farstad M.H., Svenum I.-H., Strømsheim M.D., Niemantsverdriet J.W., Venvik H.J. // Catal. Today. 2020. V. 342. P. 124.
  39. Tuxen A., Carenco S., Chintapalli M., Chuang C.-H., Escudero C., Pach E., Jiang P., Borondics F., Beberwyck B., Alivisatos A.P., Thornton G., Pong W.-F., Guo J., Perez R., Besenbacher F., Salmeron M. // J. Am. Chem. Soc. 2013. V. 135. № 6. P. 2273.
  40. Chen C., Wang Q., Wang G., Hou B., Jia L., Li D. // J. Phys. Chem. C. 2016. V. 120. № 17. P. 9132.
  41. Liu S., Li Y.-W., Wang J., Jiao H. // Catal. Sci. Technol. 2016. V. 6. P. 8336.
  42. Geerlings J.J.C., Zonnevylle M.C., de Groot C.P.M. // Surf. Sci. 1991. V. 241. № 3. P. 315.
  43. Ducreux O., Rebours B., Lynch J., Roy-Auberger M., Bazin D. // Oil Gas Sci. Technol. – Rev. IFP. 2009. V. 64. № 1. P. 49.
  44. Gnanamani M.K., Jacobs G., Graham U.M., Ribeiro M.C., Noronha F.B., Shafer W.D., Davis B.H. // Catal. Today. 2016. V. 261. P. 40.
  45. Pei Y.P., Liu J.X., Zhao Y.H., Ding Y.J., Liu T., Dong W. Da, Zhu H.J., Su H.Y., Yan L., Li J.L. // ACS Catal. 2015. V. 5. P. 3620.
  46. Qi Z., Chen L., Zhang S., Su J., Somorjai G.A. // Appl. Catal. A: Gen. 2020. V. 602, P. 117701.
  47. Fang X., Liu B., Cao K., Yang P., Zhao Q., Jiang F., Xu Y., Chen R., Liu X. // ACS Catal. 2020. V. 10. № 4. P. 2799.
  48. Lee W.H., Bartholomew C.H. // J. Catal. 1989. V. 120. № 1. P. 256.
  49. Lapidus A., Krylova A., Rathousky J., Zukal A., Jancalkova M. // Appl. Catal. A: Gen. 1992. V. 80. № 1. P. 1.
  50. Shiba N.C., Yao Y., Forbes R.P., Okoye-Chine C.G., Liu X., Hildebrandt D. // Fuel Proc. Technol. 2021. V. 216. Art. 106781.
  51. Sexton B.A., Hughes A.E., Turney T.W. // J. Catal. 1986. V. 97. P. 390.
  52. Cherepanova S.V., Koemets E.G., Gerasimov E.Yu., Simentsova I.I., Bulavchenko O.A. // Materials. 2023. V. 16. P. 6216.
  53. Khodakov A.Y., Lynch J., Bazin D., Rebours B., Zanier N., Moisson B., Chaumette P. // J. Catal. 1997. V. 168 P. 16.
  54. Puskas I., Fleisch T.H., Full P.R., Kaduk J.A., Marshall C.L., Meyers B.L. // Appl. Catal. A: Gen. 2006. V. 311. P. 146.
  55. Li C., Wong L., Tang L., Scarlett N.V.Y., Chiang K., Patel J., Burke N., Sage V. // Appl. Catal. A: Gen. 2017. V. 537. P. 1.
  56. Chu W., Chernavskii P.A., Gengembre L., Pankina G.A., Fongarland P., Khodakov A.Y. // J. Catal. 2007. V. 252. № 2. P. 215.
  57. Jacobs G., Ma W., Gao P., Todic B., Bhatelia T., Bukur D.B., Davis B.H. // Catal. Today. 2013. V. 214. P. 100.
  58. Lapidus A., Krylova A., Kazanskii V., Borovkov V., Zaitsev A., Rathousky J., Zukal A., Jancalkova M. // Appl. Catal. A: Gen. 1991. V. 73. № 1. P. 65.
  59. Borg Ø., Eri S., Blekkan E.A., Storsæter S., Wigum H., Rytter E., Holmen A. // J. Catal. 2007. V. 248. № 1. P. 89.
  60. Rane S., Borg Ø., Rytter E., Holmen A. // Appl. Catal. A: Gen. 2012. V. 437. P. 10.
  61. Хасин А.А., Юрьева Т.М., Пармон В.Н. // Доклады Академии наук. 1999. Т. 367. № 3. С. 367.
  62. Clarkson J., Ellis P.R., Humble R., Kelly G.J., McKenna M., West J. // Appl. Catal. A: Gen. 2018. V. 550. P. 28.
  63. Shimura K., Miyazawa T., Hanaoka T., Hirata S. // J. Mol. Catal. A: Chem. 2014. V. 394. P. 22.
  64. Park J.-Y., Lee Y.-J., Karandikar P.R., Jun K.-W., Ha K.-S., Park H.-G. // Appl. Catal. A: Gen. 2012. V. 411–412. P. 15.
  65. Ji L., Lin J., Zeng H.C. // J. Phys. Chem. B. 2000. V. 104. № 8. P. 1783.
  66. Rahmati M., Huang B., Mortensen M.K., Keyvanloo K., Fletcher T.H., Woodfield B.F., Hecker W.C., Argyle M.D. // J. Catal. 2018. V. 359. P. 92.
  67. Bolt P.H., Habraken F.H.P.M., Geus J.W. // J. Solid State Chem. 1998. V. 135. № 1. P. 59.
  68. Zhang J., Chen J., Ren J., Sun Y. // Appl. Catal. A: Gen. 2003 V. 243. № 1. P. 121.
  69. Paredes-Nunez A., Lorito D., Guilhaume N., Mirodatos C., Schuurman Y., Meunier F.C. // Catal. Today. 2015. V. 242. P. 178.
  70. Szanyi J., Kwak J.H. // Phys. Chem. Chem. Phys. 2014. V. 16. P. 15117.
  71. Shopska M.G., Shtereva I.Z., Kolev H.G., Tenchev K.K., Todorova S.Z., Kadinov G.B. // Croat. Chem. Acta. 2020. V. 93. № 2. P. 121.
  72. Weilach C., Spiel C., Föttinger K., Rupprechter G. // Surf. Sci. 2011. V. 605. № 15–16. P. 1503.
  73. Liu Y., Jia L., Hou B., Sun D., Li D. // Appl. Catal. A: Gen. 2017. V. 530. P. 30.
  74. Wang J., Wang J., Huang X., Chen C., Ma Z., Jia L., Hou B., Li D. // Int. J. Hydrogen Energy. 2018. V. 43. № 29. Р. 13122.
  75. Fratalocchi L., Visconti C.G, Lietti L. // Appl. Catal. A: Gen. 2020. V. 595. Art. 117514.

Supplementary files

Supplementary Files
Action
1. JATS XML
Download
2. Fig. 1. Schematic representation of the relationship between the properties of the catalyst, what they are provided with, and the indicators of TFT.

Download (355KB)
Indexing metadata
3. Fig. 2. Dependence of the degree of reduction and the size of Co particles on its content and type of carrier (diagrams are constructed according to the data of [8]).

Download (225KB)
Indexing metadata
4. Fig. 3. Model of the Co/Al2O3 catalyst surface (the representation does not pretend to correspond to the actual distribution and scale).

Download (274KB)
Indexing metadata