New glasses in the MNbOF5-BaF2-InF3 (M–Mn, Cd, Zn) systems

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Abstract

The article summarizes the results of studying new glasses in the MnNbOF5-BaF2-InF3, ZnNbOF5-BaF2-InF3 and CdNbOF5-BaF2-InF3 systems. The thermal characteristics of glasses were studied, the role of fluorindate and fluoroniobate components in glass formation and crystallization behavior was revealed. Glasses in the MNbOF5-BaF2-InF3 systems can be considered three-component; their structure is formed by polyhedra of fluoroniobate (NbO2F4 and NbO3F3), InF6 and polyhedra formed by MFn. The possibility of obtaining glass ceramics has been demonstrated. For glasses in the CdNbOF5-BaF2-InF3 and ZnNbOF5-BaF2-InF3 systems, the photoluminescence was detected corresponding to emission levels of 542, 573 and 673, 751 nm, depending on the presence and concentration of indium trifluoride in the glass. Luminescent properties are shown only by glasses in which nanoparticles, 9–13 nm, were detected according to SAXS data.

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About the authors

L. N. Ignatieva

Institute of Chemistry, FEB RAS

Author for correspondence.
Email: ignatieva@ich.dvo.ru

Doctor of Sciences in Chemistry, Chief Researcher

Russian Federation, Vladivostok

N. N. Savchenko

Institute of Chemistry, FEB RAS

Email: savchenko@ich.dvo.ru

Researcher

Russian Federation, Vladivostok

Yu. V. Marchenko

Institute of Chemistry, FEB RAS

Email: gor_dvo@mail.ru
ORCID iD: 0000-0002-0494-9948

Candidate of Sciences in Chemistry, Senior Researcher

Russian Federation, Vladivostok

V. А. Mashchenko

Institute of Chemistry, FEB RAS

Email: mashchenko@ich.dvo.ru

Researcher

Russian Federation, Vladivostok

S. A. Sarin

Institute of Chemistry, FEB RAS

Email: sarin@ich.dvo.ru

Researcher

Russian Federation, Vladivostok

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Supplementary files

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2. Fig. 1. DSC curves of samples in the MNbOF5-BaF2-InF3 (Mn, Cd, Zn) systems

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3. Fig. 2. Diffraction patterns of samples obtained after heat treatment of the initial glasses in the MNbOF5-BaF2-InF3 (M = Zn, Mn, Cd) systems under different conditions and temperatures

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4. Fig. 3. IR spectra of glasses: 1 – 30MnNbOF5-50BaF2-20InF3; 2 – 30CdNbOF5-50BaF2-20InF; 3 – 30ZnNbOF5-50BaF2-20InF3

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5. Fig. 4. Raman spectrum of 30MnNbOF5-50BaF2-20InF3 glass

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6. Fig. 5. Inelastic light scattering spectra of glasses in the ZnNbOF5-BaF2-InF3 and CdNbOF5-BaF2-InF3 systems

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7. Fig. 6. Luminescence spectra of glasses: 1 – 50ZnNbOF5-50BaF2; 2 – 50ZnNbOF5-40BaF2-10InF3; 3 – 20ZnNbOF5-40BaF2-40InF3; 4 – 20ZnNbOF5-30BaF2-50InF3 at excitation λ = 470 and 480 nm.

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8. Fig. 7. Small-angle X-ray scattering diffraction patterns of glasses in the system: a – 30ZnNbOF5-50BaF2-20InF3, b – 30CdNbOF5-50BaF2-20InF3; c – 30MnNbOF5-50BaF2-20InF3

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