Effect of conditions for obtaining detonation nanodiamond on surface composition and stability of its aqueous sols

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In present work, the effect of additional treatment of detonation nanodiamond (DND) powder of basic purification on the surface composition of DND particles, their electrokinetic properties, as well as aggregate stability in solutions of indifferent electrolyte (NaCl) in a wide pH range was studied. It has been found that a higher degree of purification of the samples and an increase in the number of protonated carboxyl groups on the surface of the DND particles due to additional acid and thermoammonia treatment leads to a shift in the position of the isoelectric point (IET) from pH 7.0 for the initial sample to pH 6.3 and pH 6.0, respectively. It is shown that the coagulation thresholds of hydrosols at natural pH and the position of stability zones in 10–3 M sodium chloride solution are in full compliance with the IET values. The highest thresholds are observed at pH 5.8 for the initial DND, while for the dispersion of DND particles after thermoammonia treatment, fast coagulation occurs already at a concentration of 10–4 M. It is also shown that the aggregate stability zones for additionally treated DND samples almost coincide. In the case of DND of basic purification, the stability zone expands in the area of positive zeta-potential, and in the area of negative values stability is not observed, probably due to the partial dissolution of surface impurities at high pH and their transition in ionic form to the solution, which causes coagulation of DND particles.

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A. Volkova

Санкт-Петербургский государственный университет

编辑信件的主要联系方式.
Email: anna.volkova@spbu.ru
俄罗斯联邦, 199034, Санкт-Петербург, Университетская наб., 7-9

D. Savelev

Санкт-Петербургский государственный университет

Email: anna.volkova@spbu.ru
俄罗斯联邦, 199034, Санкт-Петербург, Университетская наб., 7-9

N. Chuikov

Санкт-Петербургский государственный университет

Email: anna.volkova@spbu.ru
俄罗斯联邦, 199034, Санкт-Петербург, Университетская наб., 7-9

V. Vodolazhskii

Санкт-Петербургский государственный университет

Email: anna.volkova@spbu.ru
俄罗斯联邦, 199034, Санкт-Петербург, Университетская наб., 7-9

L. Ermakova

Санкт-Петербургский государственный университет

Email: anna.volkova@spbu.ru
俄罗斯联邦, 199034, Санкт-Петербург, Университетская наб., 7-9

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2. Fig. 1. X-ray radiographs of detonation nanodiamond powders.

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3. Fig. 2. Relative content of some elements on the surface of DHA particles.

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4. Fig. 3. Infrared absorption spectrum of DHA powders with base line subtraction and fitting to the maximum in the region

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5. Fig. 4. Raman spectrum of DHA powders.

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6. Fig. 5. X-ray photoelectron spectra of C1s of DHA (a) and DHA-K (b) powders.

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7. Fig. 6. X-ray photoelectron spectra of C1s of DHA powders.

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8. Fig. 7. X-ray photoelectron spectra of O1s of DHA powders.

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9. Fig. 8. Dependence of electrophoretic mobility (Ue) and electrokinetic potential (ζS) of hydrosol particles of different DHA samples on pH 10-3 M sodium chloride solution.

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10. Fig. 9. Dependence of optical density of aqueous detonation diamond sols on pH 10-3 M sodium chloride solution for 15 min of observation.

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11. Fig. 10. Dependence of the average size of DHA particles determined from the scattered light intensity size distributions on the pH of 10-3 M sodium chloride solution for 20 minutes of observation.

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12. Fig. 11: Dependence of optical density of DHA hydrosol on observation time at different concentrations of sodium chloride solutions and natural pH value.

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13. Fig. 12. Dependence of optical density of DHA-K hydrosol on observation time at different concentrations of sodium chloride solutions and natural pH value.

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14. Fig. 13. Dependence of optical density of DHA-TA hydrosol on observation time at different concentrations of sodium chloride solutions and natural pH value.

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15. Fig. 14. Dependence of the average particle size dI on the concentration of NaCl solutions at natural pH value. Numerical values at dots are the fraction (%) of light intensity scattered by particles of a given size (given for the case of bimodal distribution).

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16. Fig. 15: Dependence of electrophoretic mobility (Ue) and electrokinetic potential (ζS) of hydrosol particles of different DHA samples on the concentration of sodium chloride solutions at natural pH value.

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17. Tabl. 1.

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18. Tabl. 2.

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19. Tabl. 3.

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