Heterogeneous-catalytic reaction of hydrogenation-dehydrogenation of aromatic compounds as the basis of accumulation, storage, and production of chemically pure hydrogen

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Resumo

The quality of hydrogen released from naphthenic substrates (bicyclohexyl, ortho-, meta-, and para-isomers of perhydroterphenyl) as a result of catalytic dehydrogenation over 3% Pt/C (sibunit) is studied as a key criterion for the high degree of regeneration and recyclization of hydrogen storage systems. It is shown that chemically pure hydrogen without impurities of methane and carbon oxides can be obtained by the dehydrogenation of liquid organic hydrogen carriers (LOHC) if the initial aromatic hydrocarbons and the naphthenic substrates obtained from them were previously thoroughly thermally treated before the hydrogenation and dehydrogenation reactions, respectively, in an inert gas.

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Sobre autores

А. Каlenchuk

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Autor responsável pela correspondência
Email: akalenchuk@yandex.ru
Rússia, 119992, Moscow; 119991, Moscow

V. Bogdan

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
Rússia, 119992, Moscow; 119991, Moscow

L. Kustov

M. V. Lomonosov Moscow State University; N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: akalenchuk@yandex.ru
Rússia, 119992, Moscow; 119991, Moscow

He Teng

Dalian Institute of Chemical Physics

Email: akalenchuk@yandex.ru
República Popular da China, Dalian

Bibliografia

  1. Reuß M., Grube Th., Robinius M. et al. // Appl. Energy. 2017. V. 200. P. 290.
  2. Preuster P., Alekseev A., Wasserscheid P. // Annu. Rev. Chem. Biomol. Eng. 2017. V. 8. P. 445.
  3. Rao P.Ch., Yoon M. // Energies. 2020. V. 13. P. 6040.
  4. Makaryan I.A., Sedova I.V., Maksimov A.L. // Rus. J. Appl. Chem. 2020. V. 93. N. 12. P. 1815.
  5. Jorschick H., Geißelbrecht M., Eßl M. et al. // Int. J. Hydrogen Energy. 2020. V. 45. P. 14897.
  6. Дубинин А.М., Финк А.В, Кагарманов Г.Р. // Промышленная энергетика. 2007. № 5. С. 32.
  7. Хоффман Е. Энерготехнологическое использование угля. М.: Энергоиздат, 1983. 328 C.
  8. Иоффе В.Б. Основы производства водорода. Л.: Гостехиздат, 1960. 427 C.
  9. Bulgarin A., Jorschick H., Preuster P. et al. // Int. J. Hydrogen Energy. 2020. V. 45. P. 712.
  10. Якименко Л.М., Модылевская И.Д., Ткачек З.Я. Электролиз воды. М.: Химия. 1970. 318 C.
  11. Tremel A., Wasserscheid P., Baldauf M., Hammer T. // Int. J. Hydrogen Energy. 2015. V. 40. P. 11457.
  12. Cipriani G., Di Dio V., Genduso F., La Cascia D. // Int. J. Hydrogen Energy. 2014. V. 39. P. 8482.
  13. Sekine Y., Higo T. // Topics in Catalysis. 2021. V. 64. P. 470.
  14. Cho J.-Y., Kim H., O J.-E., Park B.Y. // Catalysts. 2021. V. 11. P. 14971525.
  15. Кустов Л.М., Каленчук А.Н., Богдан В.И. // Успехи химии. 2020. Т. 89. С. 897.
  16. Ren J., Musyoka N.M., Langmi H.W. et al. // Int. J. Hydrogen Energy. 2017. V. 42. P. 289.
  17. Kalenchuk A.N., Bogdan V.I., Dunaev S.F., Kustov L.M. // Int. J. Hydrogen Energy. 2018. V. 43. P. 6191.
  18. Каленчук А.Н., Богдан В.И., Кустов Л.М. // Журн.физ. химии. 2015. Т. 89. С. 20.
  19. Кalenchuk А.N., Bogdan V.I., Dunaev S.F., Кustov L.М. // Fuel. 2020. V. 280. № 15. P. 118625.
  20. Кalenchuk А.N., Кustov L.М. // Molecules. 2022. V. 27. № 7. P. 2236.
  21. Кustov L.M., Кalenchuk A.N., Dunaev S.F., Bogdan V.I. // Mendeleev Commun. 2019. V. 29. P. 25.
  22. Цырульников П.Г., Иост К.Н., Шитова Н.Б., Темерев В.Л. // Катал. хим. нефтехим. пром. 2016. Т. 16. С. 20.
  23. Каленчук А.Н., Маслаков К.И., Богдан Т.В. и др. // Изв. АН. 2021. T. 2. 323.
  24. Goethel P.J., Yang R.T. // J. Catal. 1988. V. 111. P. 220.
  25. Bogdan V.I., Kalenchuk A.N., Chernavsky P.A. et al. // Int. J. Hydrogen Energy. 2021. V. 46. № 1. P. 1.

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2. Fig. 1. Chromatogram of gaseous products of the dehydrogenation reaction.

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