Study of the Reversible Hawthorne Rearrangement between Isomeric Forms of the Octadecahydroeicosaborate Anion using Dynamic 11B NMR Spectroscopy
- Авторлар: Dontsova O.S.1, Matveev E.Y.1,2, Eshtukova-Shcheglova E.A.1, Nichugovskii A.I.1, Golubev A.V.2, Privalov V.I.2, Avdeeva V.V.2, Malinina E.A.2, Zhizhin K.Y.1,2, Kuznetsov N.T.1,2
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Мекемелер:
- MIREA — Russian Technological University, Institute of Fine Chemical Technologies named after M.V. Lomonosov
- Kurnakov Institute of General and Inorganic Chemistry
- Шығарылым: Том 69, № 6 (2024)
- Беттер: 816-821
- Бөлім: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://permmedjournal.ru/0044-457X/article/view/666491
- DOI: https://doi.org/10.31857/S0044457X24060033
- EDN: https://elibrary.ru/XTQACF
- ID: 666491
Дәйексөз келтіру
Аннотация
The process of rearrangement of the octadecahydroeicosaborate anion [trans-B20H18]2– → [iso-B20H18]2– in various solvents (acetonitrile, DMF, DMSO) under UV irradiation in dynamics has been studied using 11B NMR spectroscopy. It has been shown that the time of complete isomeric transition depends on the solvent used. In acetonitrile, complete conversion of the [trans-B20H18]2– anion to the iso form is achieved in 1 h; in DMF, the process takes about 2 h; in DMSO, about 3 h. The reverse process of rearrangement of the macropolyhedral borohydride anion [iso-B20H18]2– → [trans-B20H18]2– has been studied under the influence of temperature in DMF and it has been shown that an increase in the reaction time and an increase in the temperature of the reaction solution is accompanied by degradation of the boron cluster.
Негізгі сөздер
Толық мәтін

Авторлар туралы
O. Dontsova
MIREA — Russian Technological University, Institute of Fine Chemical Technologies named after M.V. Lomonosov
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119571
E. Matveev
MIREA — Russian Technological University, Institute of Fine Chemical Technologies named after M.V. Lomonosov; Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119571; Moscow, 119991
E. Eshtukova-Shcheglova
MIREA — Russian Technological University, Institute of Fine Chemical Technologies named after M.V. Lomonosov
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119571
A. Nichugovskii
MIREA — Russian Technological University, Institute of Fine Chemical Technologies named after M.V. Lomonosov
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119571
A. Golubev
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
V. Privalov
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
V. Avdeeva
Kurnakov Institute of General and Inorganic Chemistry
Хат алмасуға жауапты Автор.
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
E. Malinina
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119991
K. Zhizhin
MIREA — Russian Technological University, Institute of Fine Chemical Technologies named after M.V. Lomonosov; Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119571; Moscow, 119991
N. Kuznetsov
MIREA — Russian Technological University, Institute of Fine Chemical Technologies named after M.V. Lomonosov; Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Ресей, Moscow, 119571; Moscow, 119991
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