Synthesis and structure of gold(III) compounds with i-Pr- and t-Bu- substituted tetraarylporphyrins

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Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Gold(III) compounds with tetrakis-(4-tert-butylphenyl)porphyrin, [Au(TTBPP)][AuCl4] (I), and with tetrakis-(4-isopropylphenyl)porphyrin, [Au(TIPPP)][AuCl4] (II), were synthesized for the first time. The obtained compounds were characterized by elemental analysis,1H NMR spectroscopy, cyclic voltammetry, and X-ray diffraction analysis of solvated complexes (CCDC no. 2333206 (Ia) and 2333207 (IIa)). Study of the structures of the obtained gold(III) complexes confirmed their specific character consisting in the formation of additional Au⋅⋅⋅Au and Au⋅⋅⋅Cl contacts between neighboring complexes giving weak intermolecular bonds.

Толық мәтін

Рұқсат жабық

Авторлар туралы

E. Bardina

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Ресей, Novosibirsk

E. Makotchenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Ресей, Novosibirsk

K. Birin

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Ресей, Moscow

E. Shremzer

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Ресей, Moscow

P. Abramov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Ресей, Novosibirsk

Yu. Gorbunova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

Email: gushchin@niic.nsc.ru
Ресей, Moscow; Moscow

A. Gushchin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: gushchin@niic.nsc.ru
Ресей, Novosibirsk

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Әрекет
1. JATS XML
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2. Sch. 1. Structure of porphyrins and their abbreviation.

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3. Sch. 2. Synthesis of compounds I and II.

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4. Fig. 1. ESP of TTBPPPH2 and [Au(TTBPPP)][AuCl4] (I) in CH2Cl2.

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5. Fig. 2. ESP of TIPPPPPH2 and [Au(TIPPPP)][AuCl4] (II) in CH2Cl2.

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6. Fig. 3. Molecular structure of the complex cation in structure Ia according to PCA data.

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7. Fig. 4. Molecular structure of the complex cation in structure IIa according to PCA data.

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8. Fig. 5. Fragment of crystal structure Ia. Au⋅⋅⋅⋅Au and Au⋅⋅⋅⋅Cl contacts are shown by dashed lines.

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9. Fig. 6. Fragment of the crystal structure IIa. The Au⋅⋅⋅⋅Au and Au⋅⋅⋅⋅Cl contacts are shown by dashed lines.

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