Investigation of the properties of soft carbons and graphite by electrochemical impedance spectroscopy. Analysis of the distribution function of relaxation times

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In this work, using the Distribution of Relaxation Times (DRT) function, we analyzed the changes in the electrochemical impedance spectra of lithium-carbon cells during cathodic polarization of a carbon electrode. Soft carbon and graphite were studied as carbon materials. It is shown that the analysis of electrochemical impedance spectra of lithium-carbon cells using the distribution function of relaxation times allows us to establish the number of electrochemical elements and calculate their parameters. Application of DRT functions for modeling of electrochemical impedance showed that there are 8 electrochemical elements in lithium-carbon cells and allowed to quantify their parameters. The obtained results are in good agreement with theoretical ideas about the structure of carbon materials and electrochemical processes occurring during their polarization. The analysis of electrochemical impedance spectra of lithium-carbon cells using the relaxation time distribution function is a more objective method compared to the method of equivalent electrical circuits.

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D. Kolosnitsyn

Ufa Federal Research Centre of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: dkolosnitsyn@gmail.com

Ufa Institute of Chemistry

俄罗斯联邦, Ufa

E. Kuzmina

Ufa Federal Research Centre of the Russian Academy of Sciences

Email: dkolosnitsyn@gmail.com

Ufa Institute of Chemistry

俄罗斯联邦, Ufa

N. Egorova

Ufa Federal Research Centre of the Russian Academy of Sciences

Email: dkolosnitsyn@gmail.com

Ufa

俄罗斯联邦, Ufa Institute of Chemistry

V. Kolosnitsyn

Ufa Federal Research Centre of the Russian Academy of Sciences

Email: dkolosnitsyn@gmail.com

Ufa Institute of Chemistry

俄罗斯联邦, Ufa

参考

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2. Fig. 1. Chronopotentiograms of cathodic polarization at the first and second cycles of a carbon electrode based on disordered carbon (a) and graphite (b).

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3. Fig. 2. Evolution of impedance hodographs of lithium-carbon cells with working electrodes based on disordered carbon (left column) and graphite (right column) during lithiation at the 1st cycle. Ik=0.2 mA/cm2. The depth of lithiation is indicated in the graphs.

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4. Fig. 3. DRT impedance functions of lithium-RU, lithium-graphite and symmetric lithium-lithium cell after assembly. The electrochemical system is indicated in the graphs.

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5. Fig. 4. Experimental impedance hodographs of lithium-carbon cells with electrodes based on RU (a) and graphite (c) at lithiation depths of 428 and 410 mA h/g, hodographs of individual cell elements calculated from DRT functions, and simulated impedance hodographs of lithium-carbon cells with electrodes based on RU (c) and graphite (d).

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6. Fig. 5. Variation of DRT impedance function plots (in different scales) of a lithium-carbon cell with an RU-based electrode during lithiation at the first (left column) and second (right column) cycles. The depth of lithiation is indicated in the graphs.

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7. Fig. 6. Variation of DRT impedance function plots (at different scales) of a lithium-carbon cell with graphite-based electrode during lithiation at the first (left column) and second (right column) cycles. The depth of lithiation is indicated on the graphs.

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