Catalytic properties of cerium oxide formed on titanium by plasma electrolytic oxidation

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Abstract

A comparative analysis of the catalytic properties of Ce-containing composites 2.5% Ce-TiO2/Ti and 10.5 %Ce-TiO2/Ti has been performed in oxidative desulfurization reactions. TiO2/Ti-supported catalysts with low and high cerium concentrations (2.4–2.6 and 8.7–12.4 at. % Ce, respectively) have been obtained by plasma electrolytic oxidation (PEO) in electrolytes containing equal (0.05 mol/L) concentrations of Ce2(SO4)3 and Ce(SO4)2. It was found that Ce(SO4)2 use can increase the cerium concentration in the composites and respectively their activity in the of methyl phenyl sulfide oxidation by hydrogen peroxide. Moreover, the use of 10.5% Ce-TiO2/Ti catalyst allows almost complete oxidation of dibenzothiophene with atmospheric oxygen at 130°C in 3 h.

About the authors

I. G. Tarkhanova

Moscow State University

Author for correspondence.
Email: itar_msu@mail.ru
ORCID iD: 0000-0002-6347-7346

Doctor of Chemical Sciences, Leading Researcher, Department of Chemical Kinetics, Faculty of Chemistry

Russian Federation, Leninskie gory, 1/3, Moscow, 119991

E. A. Eseeva

Moscow State University

Email: itar_msu@mail.ru
ORCID iD: 0000-0001-7538-9012

PhD, Senior Researcher, Department of Oil Chemistry and Organic Catalysis, Faculty of Chemistry

Russian Federation, Leninskie gory, 1/3, Moscow, 119991

M. O. Lukashov

Moscow State University

Email: itar_msu@mail.ru
ORCID iD: 0000-0002-4656-6232

Postgraduate student of the Department of Oil Chemistry and Organic Catalysis, Faculty of Chemistry

Russian Federation, Leninskie gory, 1/3, Moscow, 119991

T. P. Yarovaya

Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences

Email: itar_msu@mail.ru
ORCID iD: 0000-0002-8358-1095

Researcher, Laboratory of Electrochemical Processes, Department of Electrochemical Systems and Surface Modification Processes

Russian Federation, prosp. 100-letiya Vladivostoka, 159, Vladivostok, 690022

I. V. Lukiyanchuk

Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences

Email: itar_msu@mail.ru
ORCID iD: 0000-0003-1680-4882

PhD, Senior Researcher, Laboratory of Electrochemical Processes, Department of Electrochemical Systems and Surface Modification Processes

Russian Federation, prosp. 100-letiya Vladivostoka, 159, Vladivostok, 690022

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