电邮这篇文章 para-substituted anilines in reactions with tropyl salts and dibenzosuberenol
- 作者: Akent'eva T.A1, Zhakova S.N1
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隶属关系:
- Perm State Agro-Technological University Named after Academician D.N. Pryanishnikov
- 期: 卷 59, 编号 7 (2023)
- 页面: 956-960
- 栏目: Articles
- URL: https://permmedjournal.ru/0514-7492/article/view/666240
- DOI: https://doi.org/10.31857/S0514749223070108
- EDN: https://elibrary.ru/HTSEXS
- ID: 666240
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详细
The features of the interaction of para-substituted anilines with tropyl salts and dibenzosuberenol have been studied. By the interaction of para-substituted anilines with tropyl salts (perchlorate or tetrafluoroborate) in an ethanol or tetrahydrofuran medium, the corresponding azomethines were obtained instead of the expected ortho-tropylated anilines. The tropilidene cycle (1,3,5-cycloheptariene cycle) underwent benzilidene narrowing due to an increase in temperature during a chemical reaction. The structurally related tropilidene - dibenzosuberene cycle can be introduced into the ortho position of para-substituted anilines to form stable ortho products. Dibenzosuberenol in an acidic environment is able to interact with ethanol to form an ether.
作者简介
T. Akent'eva
Perm State Agro-Technological University Named after Academician D.N. Pryanishnikov
Email: akentjeva-perm@yandex.ru
S. Zhakova
Perm State Agro-Technological University Named after Academician D.N. Pryanishnikov
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