Reaction of 3-(3-arylacryloyl)-2H-chromen-2-ones with methyl 1-bromocyclopentanecarboxylate and zinc

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The Reformatsky reagent, derived from the methyl 1-bromocyclopentanecarboxylate and zinc, selectively attaches to the double carbon-carbon bond of the heterocyclic fragment 3-(3-arylacryloyl)-2H-chromen-2-ones, resulting after hydrolysis of the reaction mixture the adducts that exist in enolic form. The structure of the adducts was confirmed by X-ray diffraction analysis. The addition to the carbon-carbon bond of the acryloyl fragment or the intramolecular cyclization of the adducts was not detected, despite the use of the excess of Reformatsky reagent, increase of the temperature, and increase of the duration of heating of the reaction mixture.

作者简介

E. Nikiforova

Perm State National Research University

编辑信件的主要联系方式.
Email: vikro@ya.ru
ORCID iD: 0000-0002-0871-9154
俄罗斯联邦, ul. Bukireva, 15, Perm, 614990

D. Zverev

Perm State National Research University

Email: vikro@ya.ru
ORCID iD: 0000-0002-6060-7678
俄罗斯联邦, ul. Bukireva, 15, Perm, 614990

M. Dmitriev

Perm State National Research University

Email: vikro@ya.ru
ORCID iD: 0000-0002-8817-0543
俄罗斯联邦, ul. Bukireva, 15, Perm, 614990

N. Kirillov

Perm State National Research University

Email: vikro@ya.ru
ORCID iD: 0000-0001-6149-6829
俄罗斯联邦, ul. Bukireva, 15, Perm, 614990

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