Mössbauer studies of iron-containing oxide coatings with different Fe/Co atomic ratios formed on titanium and aluminum by plasma-electrolytic oxidation

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Abstract

In this work, iron-containing oxide coatings with different Fe/Co atomic ratios formed on titanium and aluminum in the process of plasma-electrolytic oxidation, were studied using the Mössbauer spectroscopy method. It was determined that the contribution of the high-spin spectral component of Fe(III) is minimal in the absence of cobalt and is maximum with the predominance of cobalt in coatings formed on titanium. On coatings formed on aluminum, the presence of a magnetically ordered spectral component of Fe(III) was discovered, which disappears with the predominance of cobalt in the coating.

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About the authors

Denis V. Balatskiy

Institute of Сhemistry, FEB RAS; Far Eastern Federal University

Author for correspondence.
Email: denis.balatskiy@bk.ru
ORCID iD: 0000-0001-8737-9196

Junior Researcher; Postgraduate Student

Russian Federation, Vladivostok; Vladivostok

Yulia B. Budnikova

Institute of Сhemistry, FEB RAS; Far Eastern Federal University

Email: budnikova.iub@mail.ru
ORCID iD: 0000-0002-8716-8986

Junior Researcher; Postgraduate Student

Russian Federation, Vladivostok; Vladivostok

Egor I. Sadovetc

Far Eastern Federal University

Email: sadovetc.ei@dvfu.ru

Student

Russian Federation, Vladivostok

References

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Supplementary files

Supplementary Files
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2. Fig. 1. Mössbauer spectra of the coating material formed on titanium (a) and aluminum (b) in electrolytes with different Fe/Co atomic ratios

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3. Fig. 2. Dependence of the contribution of trivalent iron states to the Mössbauer spectra of the coating material formed on titanium and aluminum on the Fe/Co ratio in electrolytes (contribution of the magnetically ordered spectral component)

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