Hybrid coatings with a self-healing effect on the surface of functional materials

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Abstract

This article provides a review of advances in self-healing hybrid coatings development used to protect functional materials in corrosive environments.Self-healing coatings are currently attracting much interest due to their ability to suppress corrosion, which is a serious problem in almost all industries. The design of smart coatings with the active anticorrosion protection and self-healing is necessary for the long-term service life of metal structures in aggressive environments. When a self-healing coating is damaged in a corrosive media a new protective layer is formed on the surface of the defect and the functional characteristics of the product are restored. Autonomous mechanisms for restoring the protective properties of anticorrosion layers activated due to introducing corrosion inhibitors into the coating matrix.

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About the authors

А. S. Gnedenkov

Institute of Chemistry, FEB RAS

Author for correspondence.
Email: asg17@mail.com
ORCID iD: 0000-0002-9822-7849

Professor of the Russian Academy of Sciences, Doctor of Sciences (Chemistry), Chief Researcher

Russian Federation, Vladivostok

S. L. Sinebryukhov

Institute of Chemistry, FEB RAS

Email: sls@ich.dvo.ru

Corresponding Member of the Russian Academy of Sciences, Doctor of Sciences (Chemistry), Associate Professor, Deputy Director

Russian Federation, Vladivostok

V. S. Marchenko

Institute of Chemistry, FEB RAS

Email: filonina.vs@gmail.com
ORCID iD: 0000-0002-9544-3597

Junior Researcher

Russian Federation, Vladivostok

A. D. Nomerovskii

Institute of Chemistry, FEB RAS

Email: nomerovskii.ad@outlook.com
ORCID iD: 0000-0002-3118-5971

Vladivostok

Russian Federation, Vladivostok

Y. I. Kononenko

Institute of Chemistry, FEB RAS

Email: yana1996i@mail.ru
ORCID iD: 0000-0002-2299-9009

Junior Researcher

Russian Federation, Vladivostok

V. I. Sergienko

Institute of Chemistry, FEB RAS

Email: referent@ich.dvo.ru
ORCID iD: 0000-0002-0547-5545

Academician of the Russian Academy of Sciences, Doctor of Sciences (Chemistry), Professor, Scientific leader of the organization

Russian Federation, Vladivostok

S. V. Gnedenkov

Institute of Chemistry, FEB RAS

Email: svg21@hotmail.com
ORCID iD: 0000-0003-1576-8680

Corresponding Member of the Russian Academy of Sciences, Doctor of Sciences (Chemistry), Professor, Director

Russian Federation, Vladivostok

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2. Fig. 1. The mechanism of corrosion degradation and protective action of coatings on magnesium alloy AM50 in NaCl solution: (a) base PEO coating, (b) PEO + GNT – PEO + halloysite nanotubes, (c) PEO + GNT + BTA – PEO + halloysite nanotubes + benzotriazole[40]

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3. Fig. 2. SEM images of hydroxyapatite (HAP) microparticles treated with inhibitors: (a) La3+, (b) Ce3+, (c) salicylaldoxime (Sal), (d) 8-hydroxyquinoline (8HQ) [42]

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4. Fig. 3. Scheme of suppression of the corrosion process due to the action of an inhibitor contained in the protective coating [43]

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5. Fig. 4. Mechanism of corrosion degradation of magnesium alloy with PEO-LDH(BTA) coating (a) and base PEO coating (b). I – a defect appears in the coating (a, b); II – initiation of the corrosion process, leading to dissolution of the magnesium matrix (a, b); diffusion of BTA into the defective zone with possible formation of Mg(BTA-H)2 (a); III – BTA molecules and the Mg(BTA-H)2 layer inhibit the corrosion process, resulting in the formation of crystalline Mg(OH)2 (a); loose Mg(OH)2 products are formed in the defective zone of the base PEO coating (b) [46]

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6. Fig. 5. The mechanism of active protection against corrosion of magnesium alloy MA8 with a coating containing a polymer and an inhibitor, at the moment of destruction of the protective layer [12]

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