Embedding of magnetoactive particles from slurry electrolytes into PEO coatings on titanium

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Abstract

The paper summarizes the literature data on plasma electrolytic treatment of titanium in electrolytes with dispersed magnetoactive particles in order to form surface structures with certain magnetic properties. The compositions of electrolytes, process parameters and magnetic properties of the resulting coatings are presented. Depending on the chemical nature and characteristics of the particles, an inert or reactive mechanism of their introduction from the electrolyte into the growing coatingsis carried out. It is shown that metal oxide particles located on the surface, mainly in pores, and in the coating bulk make the main contribution to the magnetic properties of the samples. By changing the electrolyte formula and the concentration of components, it is possible to control the composition of the particles and, accordingly, the magnetic characteristics of the coating.

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About the authors

M. V. Adigamova

Institute of Chemistry, FEB RAS

Author for correspondence.
Email: adigamova@ich.dvo.ru
ORCID iD: 0000-0002-0341-9881

Candidate of Sciences in Chemistry, Senior Researcher

Russian Federation, Vladivostok

I. V. Lukiyanchuk

Institute of Chemistry, FEB RAS

Email: lukiyanchuk@ich.dvo.ru
ORCID iD: 0000-0003-1680-4882

Candidate of Sciences in Chemistry, Senior Researcher

Russian Federation, Vladivostok

V. P. Morozova

Institute of Chemistry, FEB RAS

Email: morozova@ich.dvo.ru
ORCID iD: 0000-0003-4355-820X

Researcher

Russian Federation, Vladivostok

I. V. Malyshev

Institute of Chemistry, FEB RAS

Email: malishev@ich.dvo.ru
ORCID iD: 0000-0002-0826-0291

Candidate of Sciences in Chemistry, Researcher

Russian Federation, Vladivostok

V. S. Egorkin

Institute of Chemistry, FEB RAS

Email: egorkin@ich.dvo.ru
ORCID iD: 0000-0001-5489-6832

Candidate of Sciences in Chemistry, Senior Researcher

Russian Federation, Vladivostok

I. A. Tkachenko

Institute of Chemistry, FEB RAS

Email: tkachenko@ich.dvo.ru
ORCID iD: 0000-0002-1770-1546

Candidate of Sciences in Chemistry, Senior Researcher

Russian Federation, Vladivostok

S. L. Sinebryukhov

Institute of Chemistry, FEB RAS

Email: sls@ich.dvo.ru
ORCID iD: 0000-0002-0963-0557

Corresponding Member of RAS, Doctor of Sciences in Chemistry, Associate Professor, Deputy Director

Russian Federation, Vladivostok

S. V. Gnedenkov

Institute of Chemistry, FEB RAS

Email: svg21@hotmail.com
ORCID iD: 0000-0003-1576-8680

Corresponding Member of RAS, Doctor of Sciences in Chemistry, Professor, Director

Russian Federation, Vladivostok

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Supplementary files

Supplementary Files
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1. JATS XML
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2. Fig. 1. SEM images of the surface and pores of PEO coatings formed for 5 min in electrolytes containing PBWFe (a, g), PBWCo (b, d) and PBWNi (c, e) hydroxides.

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3. Fig. 2. Dependences of the magnetization of samples on the magnitude of the external magnetic field at 300 K (a), the surface relief of the Fe-containing sample (b) and the corresponding distribution of magnetic field lines (c)

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4. Fig. 3. SEM images of pores of coatings formed on titanium for 10 min in PBWFeCo (a), PBWFeNi (b) and PBWCoNi (c) electrolytes. Field dependences of magnetization of samples are shown (d)

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5. Fig. 4. Effect of electrolyte composition on the concentration of Fe and Co in coating pores (a), coercive force and saturation magnetization (b)

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6. Fig. 5. SEM image of powder (insert) and cobalt particle size distribution (a). Field and temperature (insert) dependences of sample magnetization are shown (b)

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7. Fig. 6. Distribution of LMO particles by size (a), magnetic properties of synthesized powders (b) and PEO layers formed in electrolyte suspensions (c)

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