Inorganic sorbents for water purification from petroleum products based on mineral and technogenic raw materials: production, application, regeneration

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Abstract

The article presents a review of the main trends in the development of sorption methods for cleaning water bodies from oil and oil products using mineral sorbents. Based on an analysis of literature data primarily from the last two decades, including the results of their own research by the authors, natural and artificial sorbents and their modifications are described. Methods and devices for obtaining sorption materials, features of their practical application, and the results of studying their basic properties are considered. The need to develop methods for regenerating spent sorbents is substantiated. The prospects for using mineral materials of natural and technogenic origin as a basis for creating new effective oil product sorbents are shown.

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About the authors

O. N. Tsybulskaya

Institute of Chemistry, FEB RAS

Author for correspondence.
Email: ont55@mail.ru
ORCID iD: 0000-0003-4215-7041

Candidate of Sciences in Engineering, Senior Researcher

Russian Federation, Vladivostok

T. V. Ksenik

Institute of Chemistry, FEB RAS

Email: tksenik2609@mail.ru
ORCID iD: 0000-0003-3578-7096

Researcher

Russian Federation, Vladivostok

A. А. Yudakov

Institute of Chemistry, FEB RAS

Email: etcih@mail.ru
ORCID iD: 0000-0002-7264-2761

Doctor of Sciences in Engineering, Chief Researcher

Russian Federation, Vladivostok

A. V. Perfilev

Institute of Chemistry, FEB RAS

Email: a.v.perfilev@mail.ru
ORCID iD: 0000-0002-9331-2710

Candidate of Sciences in Chemistry, Senior Researcher

Russian Federation, Vladivostok

References

  1. Federal’naya sluzhba gosudarstvennoy statistiki: Sotsial’no-ekonomicheskoye polozheniye Rossii = [Federal State Statistics Service: Socio-economic situation in Russia]. Moscow; 2023. 360 s. URL: https://rosstat.gov.ru/storage/mediabank/osn-12-2023.pdf (data obrashcheniya: 25.06.2024). (In Russ.).
  2. Postanovleniye Pravitel’stva RF ot 31 dekabrya 2020 g. N 2451 (S izmeneniyami i dopolneniyami ot 11 dekabrya 2023 g.) = [Decree of the Government of the Russian Federation of December 31, 2020 N 2451 (As amended and supplemented on December 11, 2023)]. 2020. 18 s. URL: http://publication.pravo.gov.ru/Document/View/0001202101090019?index=1 (data obrashcheniya: 25.06.2024). (In Russ.).
  3. Sharma V., Ramish A., Sahu O. Oil spill recovery techniques in petroleum industry: A review on treatment process. Journal of Oil, Gas and Petrochemical Sciences. 2021;3(1):1–5.
  4. Asadpour R., Sapari N., Tuan Z., Jusoh H., Riahi A., Uka O. Application of Sorbent materials in Oil Spill management: A review. Caspian Journal of Applied Sciences Research. 2013;(2):46–58.
  5. Hoang A.T., Nguyen X.P., Duong X.Q., Huynh T.T. Sorbent-based devices for the removal of spilled oil from water: A review. Environmental Science and Pollution Research. 2021;28:28876–28910.
  6. Kamenshchikov F.A., Bogomol’nyy Ye.I. Neftyanyye sorbenty = [Oilsorbents]. Moskva; Izhevsk: Institut Komp’yuternykh Issledovaniy; 2003. 268 s. (In Russ.).
  7. Malyshkina E.S. Klassifikatsiya sorbentov, ispol’zuyemykh v tekhnologiyakh ochistki stochnykh vod ot nefteproduktov = [Classification of sorbents used in wastewater treatment technologies from petroleum products]. Gradostroitel’stvo i Arkhitektura. 2020;10(3):26–34. (In Russ.).
  8. Bandura L., Woszuk A., Kołodynska D., Franus W. Application of Mineral Sorbents for Removal of Petroleum Substances: A Review. Minerals. 2017;7(3). 37.
  9. Karapetyan K.G., Dorosh I.V., Korshunov A.D. Obzor neorganicheskikh sorbentov dlya likvidatsii razlivov nefti = [Review of inorganic sorbents for oil spill response]. Yuzhno-Sibirskiy Nauchnyy Vestnik. 2023;50(4):77–88. (In Russ.).
  10. Belousov P., Rumyantseva A., Kim K., Pokidko B., Milyutin V., Izosimova Y., Tyupina E. The use of natural filtration sorbents to solve the safety problems of industrial pollution facilities. RT&A. 2023;18(5):582–587.
  11. Skirdin K.V., Kaz’mina O.V. Analiz neftesorbentov: vidy, svoystva i effektivnost’ primeneniya = [Analysis of oil sorbents: types, properties and effectiveness of use]. Neftekhimiya. 2022;62(6):797–815. (In Russ.).
  12. Vasileva J.V., Vasekha M.V., Tyulyaev V.S. Evaluation of the efficiency of sorbents for accidental oil spill response in the Arctic waters. Journal of Mining Institute. 2023;264:856–864.
  13. Pavlov A., Vasileva Z., Smirnova I. Study of sorbents of oil and oil products for emergency oil spills response in the arctic seas. IOP Conference Series: Earth and Environmental Science. 5th International Conference “Arctic: History and Modernity” 18-19 March 2020, Saint-Petersburg, Russia. 2020. 012158. doi: 10.1088/1755-1315/539/1/012158.
  14. Gubkina T.G., Belyayevskiy A.T., Masloboyev V.A. Sposoby polucheniya gidrofobnykh sorbentov nefti modifikatsiyey poverkhnosti vermikulita organosiloksanami = [Methods for producing hydrophobic oil sorbents by modifying the surface of vermiculite with organosiloxanes]. Vestnik MGTU. 2011;14(4):767–773. (In Russ.).
  15. Fokina N.V. Perspektivy ispol’zovaniya sorbentov razlichnoy modifikatsii pri ochistke prirodnykh sred ot nefteproduktov v usloviyakh Kol’skogo Severa = [Prospects for the use of sorbents of various modifications when purifying natural environments from petroleum products in the conditions of the Kola North]. Vestnik MGTU. 2019;22(1):101–108. (In Russ.).
  16. Gusev G.I., Gushchin A.A., Gordina N.E., Mel’nikov A.A., Shil’ke M.A. Ochistka stochnykh vod, soderzhashchikh nefteprodukty, sorbentom vermikulitom = [Treatment of wastewater containing petroleum products with vermiculite sorbent]. In: Innovatsionnyye tekhnologii zashchity okruzhayushchey sredy v sovremennom mire:materialy Vserossiyskoy nauchnoy konferentsii s mezhdunarodnym uchastiyem molodykh uchenykh i spetsialistov. Kazan’; 2021. S. 124–129. (In Russ.).
  17. Nguyen D.C., Bui T.T., Cho Y.B., Yong Shin Kim Y.S. Preparation of a highly porous clay-based absorbent for hazard spillage mitigation via two-step expansion of vermiculite. Minerals. 2021;11(12). 1371.
  18. Shapkin N.P., Postoykin V.V., Zav’yalov B.B., Nguyen T.N., Levchuk E.P., Kondratyuk V.A. Sposob polucheniya sorbentov dlya ochistki vody ot organicheskikh primesey: pat. 2206393 RF; zayavl. 27.08.2001; opubl. 20.06.2003, Byul. N 17. (In Russ.).
  19. Niftaliyev S.I., Peregudov Yu.S., Mokshina N.Ya., Mezhri R., Saranov I.A. Vliyaniye termicheskoy aktivatsii glaukonita na yego vlago- i nefteyomkost’ = [The influence of thermal activation of glauconite on its moisture and oil capacity]. Ekologiya i Promyshlennost’ Rossii. 2019;23(7):42–47. (In Russ.).
  20. Peregudov Yu.S., Gorbunova E.M., Mezhri R., Niftaliyev S.I. Sorbtsionnyye svoystva modifitsirovannogo glaukonita = [Sorption properties of modified glauconite]. Sorbtsionnyye i Khromatograficheskiye Protsessy. 2021;1(1):51–59. (In Russ.).
  21. Peregudov Yu.S., Mejri R., Gorbunova E.M., Niftaliev S.I. Glauconite-based sorbents for skimming oil and oil products. Condensed Matter and Interphases. 2020;22(2):257–265.
  22. Buzayeva M.V., Bulyzhev E.M., Guseva I.T., Klimov E.S. Ochistka stochnykh vod ot nefteproduktov na modifitsirovannom diatomite i regeneratsiya sorbenta = [Wastewater treatment from petroleum products using modified diatomite and sorbent regeneration]. Izvestiya Vuzov. Severo-Kavkazskiy region.Tekhnicheskiye Nauki. 2011;(4):125–127. (In Russ.).
  23. Akpomie K.G., Onyeabo C.F., Ezeofor C.C., Ani J.U., Eze S.I. Natural aluminosilicate clay obtained from south-eastern Nigeria as potential sorbent for oil spill remediation. Journal of African Earth Sciences. 2019;(155):118–123.
  24. Shachneva E.Yu. Polucheniye sorbentov na osnove mineral’nogo syr’ya = [Preparation of sorbents based on mineral raw materials]. Zhurnal Belorusskogo Gosudarstvennogo Universiteta. Ekologiya. 2022;(2):66–74. (In Russ.).
  25. Pestova N.Yu. Sistema ochistki neftesoderzhashchikh vod s pomoshchi keramzita = [Oily water purification system using expanded clay]. Yevraziyskiy Soyuz Uchenykh (YeSU). Khimicheskiye Nauki. 2016;6(27):118–120. (In Russ.).
  26. Pouraminia M., Torabiana A., Tehrani F. Application of lightweight expanded clay aggregate as sorbent for crude oil cleanup. Desalination and Water Treatment. 2019;160:366–367.
  27. Ryu С., Yeo S. Vapor phase adsorption of trichloroethane using organically modified montmorillonite. Journal of Industrial and Engineering Chemistry. 2010;16(3):441–447.
  28. Kornev V.A., Rybakov Yu.N. Montmorillonitovyye sorbenty nefteproduktov = [Montmorillonite sorbents for petroleum products]. Vestnik Nauki i Obrazovaniya. 2017;(10):20–24. (In Russ.).
  29. Kornev V.A., Rybakov Yu.N., Chirikov S.I. Sravnitel’naya otsenka struktury chastits i adsorbtsionnykh svoystv shungita i bentonita = [Comparative assessment of particle structure and adsorption properties of shungite and bentonite]. Vestnik Nauki i Obrazovaniya. 2015;9(11):20–23. (In Russ.).
  30. Kornev V.A., Rybakov Yu.N. Mineral’nyye poroshkoobraznyye sorbenty tipa bentonita dlya ustraneniya razlivov zhidkikh nefteproduktov v zonakh perekachivaniya i khraneniya topliva = [Mineral powder sorbents such as bentonite for eliminating spills of liquid petroleum products in areas of fuel pumping and storage]. Problemy Sovremennoy Nauki i Obrazovaniya. 2015;12(42):79–83. (In Russ.).
  31. Mazlova E.A., Meritsidi I.A., Blinovskaya Ya.Yu., Razmakhnin K.K., Kulikova O.A. Preimushchestva i nedostatki neftyanykh sorbentov dlya likvidatsii razlivov na akvatorii v usloviyakh nizkikh temperatur = [Advantages and disadvantages of oil sorbents for liquidation of spills in water areas at low temperatures]. Zashchita Okruzhayushchey Sredy v Neftegazovom Komplekse. 2020;6(297):55–60. (In Russ.).
  32. Obuzdina M.V. Prirodnyye i modifitsirovannyye tseolity kak adsorbenty nefteproduktov iz promyshlennykh stochnykh vod = [Natural and modified zeolites as adsorbents for oil products from industrial wastewater]. Vestnik IrGTU. 2010;4(44):104–110. (In Russ.).
  33. Dabizha O.N., Khamova T.V., Shilova O.A. Mekhanokhimicheskaya modifikatsiya tseolitovykh porod poliakrilamidom dlya polucheniya neftesorbentov = [Mechanochemical modification of zeolite rocks with polyacrylamide to obtain oil sorbents]. Neorganicheskiye Materialy. 2023;59(10):1164–1176. (In Russ.).
  34. Dabizha O.N., Khamova T.V., Shilova O.A. Mekhanokhimicheskoye modifitsirovaniye tseolitovykh porod polivinilovym spirtom dlya povysheniya ikh nefteyemkosti = [Mechanochemical modification of zeolite rocks with polyvinyl alcohol to increase their oil capacity]. Neorganicheskiye Materialy. 2022;58(12):1383–1395. (In Russ.).
  35. Vardanyan M.A. Gidrofobizatsiya vspuchennogo perlita sinteticheskimi polimernymi materialami i izucheniye yego sorbtsionnykh svoystv = [Hydrophobization of expanded perlite with synthetic polymeric materials and study of its sorption properties]. Voda i Ekologiya. 2017;(2):50–59. (In Russ.).
  36. Chernov M.A., Zamakhayev Yu.V., Kolosov G.G., Gileva L.I., Sagitova N.Z. Ustroystvo dlya gidrofobizatsii poroshkoobraznykh materialov: pat. 2544699 RF; zayavl. 02.09.2013; opubl. 20.03.2015, Byul. N 8. (In Russ.).
  37. Shvedchikov G.V. Sposob polucheniya sorbentov dlya zhidkikh uglevodorodov: pat. 2340393 RF; zayavl. 10.02.2008; opubl. 10.12.2008, Byul. N 34. (In Russ.).
  38. Gürsoya М., Karaman М. Hydrophobic coating of expanded perlite particles by plasma polymerization. Chemical Engineering Journal. 2016;284:343–350.
  39. Mesyats S.P., Ostapenko S.P. Izmeneniye morfologii poverkhnosti vermikulita dlya polucheniya sorbentov nefti na ego osnove = [Changing the morphology of the vermiculite surface to obtain oil sorbents based on it]. Vestnik MGTU. 2009;12(4):747–750. (In Russ.).
  40. Kruzhalov A.V., Romadenkina S.B., Reshetov V.A., Shchipanova M.V. Sposoby polucheniya gidrofobnykh sorbentov iz prirodnykh materialov = [Methods for producing hydrophobic sorbents from natural materials]. Izv.Sarat. Un-ta. Nov. Ser. Ser. Khimiya. Biologiya. Ekologiya. 2014;14(2):39–42. (In Russ.).
  41. Vezentsev A.I., Nguyen Kh.T., Sokolovskiy P.V., Bukhanov V.D., Milyutin V.V., Kon’kova T.V., Alekhina M.B. Kompozitsionnyy sorbent na osnove mineral’nogo i rastitel’nogo syr’ya = [Composite sorbent based on mineral and plant raw materials]. Sorbtsionnyye i Khromatograficheskiye Protsessy. 2015;15(1):127–133. (In Russ.).
  42. Peregudov Yu.S. Magnitnyye neftyanyye sorbenty na osnove tekhnogennykh i prirodnykh neorganicheskikh materialov = [Magnetic oil sorbents based on technogenic and natural inorganic materials]. Ekologiya i Promyshlennost’ Rossii. 2021;25(2):34–40. (In Russ.).
  43. Kalinina E.V., Glushankova I.S., Rudakova L.V. Modifikatsiya shlamov sodovogo proizvodstva dlya polucheniya neftyanykhs orbentov= [Modification of soda production sludge to obtain oil sorbents]. Teoreticheskaya i Prikladnaya Ekologiya. 2018;(2):79–86. (In Russ.).
  44. Nikolayeva L.A. Ochistka stochnykh vod TES ot nefteproduktov gidrofobnym karbonatnym shlamom = [Treatment of wastewater from thermal power plants from oil products using hydrophobic carbonate sludge]. Teploenergetika. 2020;(10):79–85. (In Russ.).
  45. Pabis-Mazgaj E., Pichniarczyk P., Stempkowska A., Gawenda T. Possibility of using natural zeolite waste granules obtained by pressure agglomeration as a sorbent for petroleum substances from paved surfaces. Materials. 2022;15(19). 6871.
  46. Araslanova L., Kuznetsova E., Tuktarova I., Nazarov A. Development of oil product contaminated wastewater treatment technology using sorbents based on mining waste. International Conference on Efficient Production and Processing (E3S Web of Conferences). 2020;161. 01030.
  47. Samodolova O.A., Ul’rikh D.V., Lonzinger T.M., Denisov S.E. Ispol’zovaniye penostekla (granulirovannogo) v ochistke gorodskikh poverkhnostnykh stochnykh vod = [Use of foam glass (granular) in the treatment of municipal surface wastewater]. Stroitel’stvo: Nauka i Obrazovaniye. 2023;13(2):131–143. (In Russ.).
  48. Kogan V.E., Zgonnik P.V., Shakhparonova T.S., Sobianina D.O., Suvorova Z.V. The physicochemical bases of oil and oil products absorption by glassy sorbents. Rasayan Journal of Chemistry. 2021;14(3):2006–2016.
  49. Didkovskiy A.A. Metody regeneratsii sorbentov = [Methods for regeneration of sorbents]. Sovremennyye Naukoyemkiye Tekhnologii. 2014;5(2):101–102. (In Russ.).
  50. Shevtsov M.N., Bobrovnikova M.Yu., Yerkovich O.A. Sovremennyye tekhnologii zashchity vodnykh resursov ot zagryazneniy neftegazovogo proizvodstva = [Modern technologies for protecting water resources from oil and gas production pollution]. Dal’niy Vostok: Problemy Razvitiya Arkhitekturno-Stroitel’nogo Kompleksa. 2019;(1/2):533–536. (In Russ.).
  51. Dolina L.F. Sovremennaya tekhnologiya i sooruzheniya dlya ochistki neftesoderzhashchikh stochnykh vod = [Modern technology and facilities for treating oily wastewater]. Dnepropetrovsk: Kontinent; 2005. 296 s. (In Russ.).
  52. Podvyaznikov M.L., Samonin V.V., Shevkina A.Yu.,Chentsov M.S., Ivachev Yu.Yu. New generation sorption systems. Theoretical Foundations of Chemical Engineering. 2010;(44):485–490.
  53. Gusev G.I., Gushchin A.A., Grinevich V.I., Izvekova T.V., Sharanov A.V. Vozdeystviye dielektricheskogo bar’yernogo razryada na diatomit, zagryaznennyy nefteproduktami = [Impact of dielectric barrier discharge on diatomite contaminated with petroleum products]. Sorbtsionnyye i Khromatograficheskiye Protsessy. 2021;21(1):60–68. (In Russ.).
  54. Tsybulskaya O.N., Ksenik T.V., Yudakov A.A., Kisel A.A. Development of technology of producing the hydrophobic aluminosilicate sorbents for cleaning of water objects from organic pollutions. Procedia Environmental Science, Engineering and Management. 2019;6(4):535–545.
  55. Tsybulskaya O.N., Yudakov A.A., Ksenik T.V. Intercomponent mass transfer in swirling gas-dispersion flow with counterflow of components. International Journal of Energy for a Clean Environment. 2016;(17):241–259.
  56. Yudakov A., Ksenik T., Tsybulskaya O., Kisel A. Instrumentation and features of producing the oleophilic sorbent on the perlite basis. Procedia Environmental Science, Engineering and Management. 2021;8(1):103–113.
  57. Volkov D.A., Chirikov A.Yu., Buravlov I.Yu., Perfilev A.V., Yarusova S.B., Yudakov A.A. Gazofaznaya tonkosloynaya gidrofobizatsiya alyumosilikatov v gazovoy srede uglevodorodov = [Gas-phase thin-layer hydrophobization of aluminosilicates in a gaseous medium of hydrocarbons]. Khimicheskaya Tekhnologiya. 2019;20(14):647–651. (In Russ.).
  58. Tsybulskaya O.N., Ksenik T.V., Yudakov A.A., Pavlov M.V., Pavlov V.F. The research on the sorption properties of the x-ray amorphous silica foam. Environmental Technology and Innovation. 2021;(23):101567.
  59. Tsybulskaya O.N., Ksenik T.V., Yudakov A.A., Kisel A.A., Pavlov V.F. Eks-perimental’noye polucheniye oleofil’nykh materialov na osnove otkhodov rudnogo syr’ya = [Experimental production of oleophilic materials based on ore waste]. Vestnik of the FEB RAS. 2020;6:99–108. (In Russ.).
  60. Tsybul’skaya O.N., Ksenik T.V., Yudakov A.A., Kisel’ A.A., Pavlov V.F. Mo-difitsirovannyye sorbenty iz penosilikatov. Kineticheskiye osobennosti neftepogloshcheniya = [Modified sorbents from foam silicates. Kinetic features of oil absorption]. Vestnik of the FEB RAS. 2022;(6):122–134. (In Russ.).
  61. Tsybulskaya O.N., Ksenik T.V., Yudakov A.A. Regeneratsiya oleofil’nykh alyumosilikatnykh sorbentov: tekhnologicheskiy protsess, apparaturnoye oformleniye = [Regeneration of oleophilic aluminosilicate sorbents: technological process, instrumentation]. Vestnik of the FEB RAS. 2023;6:124–134. (In Russ.).

Supplementary files

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2. Fig. 1. Basic schemes for obtaining sorbents by processing modifying substances in gas and vapor-gas phases. The processes requiring pressure control are marked with an asterisk.

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3. Fig. 2. Thermochemical modification modes

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4. Fig. 3. Oil absorption capacity of modified sorbents

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