COMPOSITE MATERIALS BASED ON MOF ZIF-8 AND IONIC LIQUID [BMIm]+[BF4]−: AN EPR STUDY USING NITROXIDE SPIN PROBES

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Abstract

A method for the controlled filling of pores in metal-organic frameworks (MOFs) with ionic liquids (ILs) is proposed, which can be applied for selective gas sorption in MOFs. Using an example of MOF ZIF-8 and IL [BMIm]+[BF4]−, the composites with different IL content were prepared upon control by electron paramagnetic resonance (EPR) of nitroxide spin probes. The effect of IL on the sorption of nitric oxide (II) into these composites was studied using inversion gas chromatography.

About the authors

N. А. Kudryavyh

International Tomography Center, Siberian Branch of the Russian Academy of Sciences

Email: mfedin@tomo.nsc.ru
Russian, 630090, Novosibirsk

М. Yu. Ivanov

International Tomography Center, Siberian Branch of the Russian Academy of Sciences

Email: mfedin@tomo.nsc.ru
Russian, 630090, Novosibirsk

А. S. Poryvaev

International Tomography Center, Siberian Branch of the Russian Academy of Sciences

Email: mfedin@tomo.nsc.ru
Russian, 630090, Novosibirsk

D. М. Polyukhov

International Tomography Center, Siberian Branch of the Russian Academy of Sciences

Email: mfedin@tomo.nsc.ru
Russian, 630090, Novosibirsk

R. Z. Sagdeev

International Tomography Center, Siberian Branch of the Russian Academy of Sciences

Email: mfedin@tomo.nsc.ru
Russian, 630090, Novosibirsk

М. V. Fedin

International Tomography Center, Siberian Branch of the Russian Academy of Sciences

Author for correspondence.
Email: mfedin@tomo.nsc.ru
Russian, 630090, Novosibirsk

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Copyright (c) 2023 Н.А. Кудрявых, М.Ю. Иванов, А.С. Порываев, Д.М. Полюхов, Р.З. Сагдеев, М.В. Федин