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No 6 (2024)

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Articles

Vortex Motion on the Surface of Shallow and Deep Water

Poplevin A.V., Levchenko A.A., Lichter A.M., Filatov S.V., Mezhov-Deglin L.P.

Abstract

The attenuation of vortex motion on the surface of shallow and deep water is investigated. The vortex flow was formed by two mutually perpendicular waves excited by plungers at a frequency of 6 Hz (wavelength λ = 5.6 cm) on the surface of water measuring 70 × 70 cm and depth h. After reaching a stationary state in the vortex system, the wave pumping was switched off, and the attenuation of the surface flow was recorded. On the surface of shallow water, λ/2π ≈ h, when the characteristic size of the vortices L exceeds the depth of the liquid, L >> h, the time dependence of the energy of the vortex flow Е(t) is described by an exponential function at all pumping levels, and the dependence of the enstrophy Ф(t) = Ω2(t) has an exponential dependence only in the range of wave vectors 0–0.3 см–1. On the surface of deep water λ/2π < h, Lh dependence Е(t) and Ф(t) are far from exponential in all ranges of wave numbers. At high pumping levels, the dependencies Е(t) and Ф(t) are nonmonotonic, which can be attributed to the influence of volumetric flows.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):3-12
pages 3-12 views

Using of Machine Learning Capabilities to Predict Double Phosphate Structures for Biomedical Applications

Kolomenskaya E.R., Butova V.V., Rusalev Y.V., Protsenko B.O., Soldatov A.V., Butakova M.A.

Abstract

In the rapidly developing field of biomedical research, the search for new materials with improved properties is crucial to moving the entire field forward. Double phosphates have generated significant interest in a wide range of applications, ranging from drug delivery systems to catalysts for biomedical reactions, and the fields of biomedicine and tissue engineering are no exception. In this article, we propose a method for finding new double phosphate materials based on machine learning, screening and applying data from structural databases, and we use this methodology combined with chemical knowledge to propose several promising materials for bone engineering. For the selected candidates, we develop a solid-phase synthesis procedure and apply physical characteristics to confirm the results. In addition, the role of microstructure, i.e. The porosity of frameworks based on these materials is discussed from a biomedical point of view, and several synthetic ways to adjust this parameter are proposed and investigated.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):13-22
pages 13-22 views

Structural Features Investigation of a Highly Dispersed NiO–SiO2 Catalyst by X-Ray Analysis of the Atomic Pair Distribution Function

Mikhnenko M.D., Cherepanova S.V., Shmakov A.N., Alekseeva M.V., Kukushkin R.G., Yakovlev V.A., Pakharukova V.P., Bulavchenko O.A.

Abstract

In the present work NiO and NiO–SiO2 were investigated by X-ray diffraction and radial atomic pair distribution methods. By X-ray diffraction method, it was determined that the NiO particle sizes have coherent scattering region of more than 100 nm, while the NiO–SiO2 sample has a particle size of about 2–3 nm. At the same time, full-profile Rietveld simulation does not describe the effects observed on diffraction: the asymmetry of peaks, the appearance of an additional shoulder of peak 111 in the area of small angles, so the radial atomic pair distribution method was used to analyze the structure. During the simulation of the experimental atomic pair distribution curve, 3 different models were used: pure NiO, a mixture of NiO and Ni2SiO4, and a modified NiO model with Si embedded in the lattice. The latter model was created based on the assumption of silicon incorporation into the NiO structure, which can be evidenced by X-ray diffraction data. According to the results of radial atomic pair distribution modeling it is the latter model that gives the best description of the observed effects: significantly increased unit cell parameter, compared to the sample without SiO2 addition, as well as decreased metal cation–oxygen distances in the structure, while cation–cation distances are increased.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):23-30
pages 23-30 views

On the Shift of the Maximum of the Polar Angular Distribution of Sputtered Atoms in the MD Model of the (001) Ni Face Sputtering

Musin A.I., Samoilov V.N.

Abstract

Using an up-to-date full molecular dynamics model of sputtering of single crystals, taking into account the incidence of ions on the surface, the peculiarities and mechanisms of atom sputtering during bombardment of the (001) Ni face with 200 eV Ar ions are studied for two target temperatures. It is shown for the first time that with an increase in the energy of sputtered atoms, not only the maximum of their polar angular distribution in the azimuthal direction toward the Wehner spots, but also the maximum of the polar angular distribution integrated over the azimuthal angles shifts first toward the normal to the surface, and then in the opposite direction. The polar distribution integrated over the azimuthal angle is formed by atoms ejecting from the surface at much larger polar angles than in the final (observed) distribution. Both effects are explained in terms of the surface mechanism of single crystal sputtering.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):31-37
pages 31-37 views

Determination of the Ion—Solid Interaction Potential from the Experiment and Its Influence on the Profiles of Implanted Particles

Zinoviev A.N., Babenko P.Y., Mikhailov V.S., Tensin D.S.

Abstract

Based on the analysis of the angular distributions of particles passing through thin gold films, the parameters of the potential that best describes the experiment are obtained. The resulting potential differs from the potential describing collisions in the gaseous phase by a noticeable change in the screening constant. The influence of the collision energy, the choice of potential, and the model of electron bremsstrahlung on the depth distribution of implanted particles is analyzed.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):38-43
pages 38-43 views

Evolution of Nanohardness of Binary Titanium-Based Solutions under High-Pressure Torsion

Zavorotnev Y.D., Davdyan G.S., Varyukhin V.N., Petrenko A.G., Tomashevskaya E.Y., Straumal B.B.

Abstract

Based on the phenomenological theory in the Landau approximation, a model has been developed to describe experiments on measuring the nanohardness of binary titanium-based solutions under high pressure torsion. Possible mechanisms for the appearance in the experiment of asymmetry of this quantity relative to the middle of the radius of a cylindrical sample are determined. Additionally, the behavior of the radial and angular components of nanohardness in the presence of a point defect in the material under study has been studied.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):44-49
pages 44-49 views

Influence of the Constant Magnetic Field on the Density of an Aging Alloy of Beryllium Bronze BrB-2

Osinskaya Y.V., Magamedova S.G., Makeev S.R.

Abstract

This paper presents the main experimental results of measuring the density of beryllium bronze BrB-2, aged in the constant magnetic field and in its absence, using the hydrostatic weighing method. The temperature and time dependences of the density of beryllium bronze BrB-2 during the decomposition of a supersaturated solid solution in a constant magnetic field of strength 557.2 kA/m were studied, at aging temperatures of 250, 300, 350 and 400°C and aging duration from 0 to 1 hour, and a comparative comparison analysis of their behavior with the corresponding microhardness dependencies was carried out. The correlation was discovered between the temperature and time dependences of the density and microhardness of beryllium bronze BrB-2, so at an aging temperature of 350°C a sharp maximum in the density of the alloy is observed, and similarly, at the same point the absolute maximum microhardness is achieved. In addition, it was found that the application of a constant magnetic field to the aging process under all heat treatment modes always leads to an increase in the density and microhardness of beryllium bronze BrB-2 compared to the density of the alloy aged in its absence. A physical interpretation is given to the observed facts and patterns. In the future, it is planned to find a correlating function between two independent measured characteristics density and microhardness, which is important for solid state physics and materials science from a scientific and practical point of view.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):50-55
pages 50-55 views

Chirality Control of Magnetic Vortices in Ferromagnetic Disk–Nanowire System

Tatarsky D.A., Skorokhodov E.V., Ermolaeva O.L., Mironov V.L., Fraerman A.A.

Abstract

The results of experimental studies and micromagnetic modeling of magnetic states in a one-dimensional array are presented. The array has the form of a chain of ferromagnetic disks coupled with a ferromagnetic nanowire made of the same material. The disks are located on opposite sides of the nanowire, which makes it possible to obtain distributions when the chiralities of the magnetic vortex shells in neighboring disks alternate, which can find application in vortex spin nanooscillators. Using the application in situ of a magnetic field to an excited objective lens using Lorentz transmission electron microscopy, it is shown that in this system it is possible to control the chiralities of the shells of magnetic vortices, which is realized by magnetization in the sample plane along various azimuthal directions. When wire magnetized along a nanowire, vortex states with opposite chiralities are realized in disks located on opposite sides of it. An antivortex is formed in the nanowire itself at the boundary with the disk, since the local direction of magnetization in the wire and in the disk are anticollinear. When magnetized perpendicular to the nanowire, states with the same chirality are realized in all disks. In this case, two perpendicular domain walls are formed between the disks in the nanowire, and the vortex in the disk is shifted to one of the edges along the nanowire.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):56-61
pages 56-61 views

Velocity Effect in Synthesis of Noncircular Nanopores by Etching Tracks of Swift Heavy Ions in Olivine

Gorbunov S.A., Babaev P.A., Volkov A.E., Voronkov R.A., Rymzhanov R.A.

Abstract

The velocity effect was studied in the synthesis of nanopores with a noncircular cross section by etching tracks of swift heavy ions in olivine. The developed atomistic model for the etching of olivine irradiated with swift heavy ions predicts the possibility of synthesizing nanopores with a noncircular cross section in it. The model consists of connected blocks that describe the sequential stages of track formation and etching. The TREKIS Monte Carlo model describes the initial electronic and lattice excitations in the nanoscale vicinity of the trajectory of an incident ion. These results are used as initial conditions for molecular dynamics simulation of structural changes along the ion trajectory. The obtained atomic coordinates after cooling of the structurally damaged area serve as the initial data for the original atomistic model of track etching in olivine. The results of the model application show that it is possible to control the cross section of these pores by changing the orientation of the crystal relative to the direction of irradiation. The presented simulation results for Xe ions demonstrate that the size of the resulting pores depends on the velocity of the incident ion, and not only on its linear energy loss.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):62-69
pages 62-69 views

Formation of coatings from accelerated ions of fluorinated fullerene C60(CF3)12

Pukha V.E., Belmesov A.A., Kabachkov E.N., Nechaev G.V., Lukina I.N., Drozdova E.I., Chernogorova O.P.

Abstract

The first results of the deposition of coatings from accelerated ions of fluorinated fullerene C60(CF3)12 are presented. The coatings were formed at room temperature on Si substrates from a beam of singly charged C60(CF3)+12 ions with an energy of 5 keV, as well as from an ion beam, which also contained doubly charged C60(CF3)122+ ions and a certain amount of ionized fragments of molecules. The properties and structure of coatings obtained from accelerated ions of fluorinated fullerene are compared with the properties and structure of coatings obtained from accelerated C60 fullerene ions under the same conditions. According to X-ray photoelectron spectroscopy, fluorinated fullerene coatings contain about 4% fluorine. Investigations of the coatings structure and chemical bonds by X-ray photoelectron spectroscopy and Raman scattering showed that the presence of fluorine leads to decrease in the content of sp3 bonds and the formation of graphite-like sp2 structures. Coating hardness (H) and Young's modulus (E) compared to C60 ion coatings decrease from 36 to 18 GPa and from 245 to 133 GPa, respectively. The H/E ratio remained the same (~0.14). Tribological tests have shown for all coatings a friction coefficient close to 0.1. Also, all coatings are characterized by very low wear, less than 10–7 mm3/N∙m for coatings obtained from C60(CF3)12 ions, the contact angle is ~76°–78°. In the absence of fluorine, for the coating obtained from C60 ions, it is ~90°.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):70-79
pages 70-79 views

Procedure for Fabrication and Characterization of Van-der-Waals Heterostructures

Shevchun A.F., Prokudina M.G., Egorov S.V., Tikhonov E.S.

Abstract

In this work we provide a step-by-step description of the technique for manufacturing various van der Waals heterostructures. First, we discuss the procedure to obtain monolayer and few-layer flakes from layered materials, in particular from graphite and hexagonal boron nitride. Next, we consider different approaches to the assembly depending on the required final device. Further, we describe in detail the procedure for making ohmic contacts and give the parameters for plasma chemistry and metal deposition. We observe the field effect in transport measurements but a number of features – a strong shift of the charge neutral point from the zero-gate voltage, a large resistance away from the charge neutral point, and low mobility – indicate a problem with the quality of the resulting devices. Nevertheless, one of the fabricated devices demonstrates reasonable quality – the maximum mobility is estimated at 15000 cm2V–1s–1, the magnetic field dependences demonstrate the quantum Hall effect, which is standard for high-quality graphene. Unexpectedly, scanning electron microscope images of the resulting devices reveal a large amount of contamination on the surface of the flakes, which may explain the corresponding quality of our devices. Preliminary results of flakes cleaning with chemical compounds and thermal treatment are given.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):80-86
pages 80-86 views

New Polymorphic Varieties of Boron Nitride with Diamond-Like TA-Type Phases

Ryashentsev D.S., Burmistrov V.A.

Abstract

In this work, a theoretical study of new polymorphic varieties of boron nitride, which have diamond-like structures with boron and nitrogen atoms in equivalent structural positions, was carried out. The model construction of new phases of boron nitride was performed in the process of crosslinking precursor nanostructures. Single-walled boron nitride nanotubes with chirality indices (3;0), (4;0), and (6;0) were chosen as precursors for the model construction of diamond-like phases. Using the density functional theory method in the generalized gradient approximation, the possibility of stable existence of three new structural varieties of boron nitride with a diamond-like structure was established: BN-TA4, BN-TA5, BN-TA6. The structure of the BN-TA7 diamond-like phase turned out to be unstable and, in the process of geometric optimization, was transformed into the initial structure, a boron nitride nanotube (6;0). As a structural characteristic, the bulk density of the new polymorphs was determined, which is in the range from 2.613 to 3.0836 g/cm3. The sublimation energy of new polymorphic varieties ranges from 17.16 to 17.63 eV/(BN). The value of the band gap near the Fermi energy varies from 5.37 to 5.74 eV.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):87-92
pages 87-92 views

Accumulation and Erase of Radiation-Induced Charge in MOS Structures

Andreev D.V.

Abstract

It is shown that when a MOS (metal–oxide–semiconductor) structure is simultaneously exposed to radiation and high-field injection of electrons, part of the radiation-induced positive charge can be erased when interacting with injected electrons, and the density of surface states can increase. These phenomena must be taken into account when operating MOS radiation sensors in high-field charge injection modes. High-field injection modes used for post-radiation erase of positive charge in MOS sensors are analyzed. It has been established that to annihilate one hole (radiation-induced positive charge), it is necessary to inject (0.5–2) × 104 electrons into the gate dielectric; the magnitude of the electric field has almost no effect on the process of erasing the radiation-induced charge.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):93-98
pages 93-98 views

Lead Slowing-Down Neutron Spectrometry II: Cross-Section Data for 243Cm(n, f), 244Cm(n, f), 245Cm(n, f), 246Cm(n, f), 247Cm(n, f), 248Cm(n, f) at Energies up to 100 keV

Koptelov E.A.

Abstract

The possibilities of lead slowing-down neutron spectrometry have been demonstrated. We present a review of the results of a series of works on measuring the fission cross-sections of curium isotopes 243Cm, 244Cm, 245Cm, 246Cm, 247Cm, 248Cm by neutrons with energies below 100 keV, performed by a joint group of researchers of INR RAS and SSC RF IPPE on the SVZ-100 neutron spectrometer. This third-generation spectrometer has a high luminosity, which made it possible to study neutron-nuclear processes in microgram samples of radioactive nuclides, which is not available in experiments using time-of-flight spectrometry. The results of work at the INR RAS–SSC RF IPPE are reflected in international nuclear databases, complement the known experimental data and in some cases indicate the need to adjust the recommended values.

Poverhnostʹ. Rentgenovskie, sinhrotronnye i nejtronnye issledovaniâ. 2024;(6):99-112
pages 99-112 views